In 2005, after four years with Aniston — and months of work alongside Angelina Jolie on the set of 'Mr. and Mrs. Smith' — Pitt announced he and the Friends actress would split. Though all parties denied Pitt had a sexual relationship with Jolie while still married to Aniston, it's been speculated that the actor was emotionally unfaithful. The split caused a media frenzy and created a new Hollywood power couple: Brangelina, who now have six kids together.
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